Mathematical definition

The law can be written as:{\displaystyle V\propto n}

or={\displaystyle {\frac {V}{n}}=k}

where

  • V is the volume of the gas;
  • n is the amount of substance of the gas (measured in moles);
  • k is a constant for a given temperature and pressure.

This law describes how, under the same condition of temperature and pressure, equal volumes of all gases contain the same number of molecules. For comparing the same substance under two different sets of conditions, the law can be usefully expressed as follows:={\displaystyle {\frac {V_{1}}{n_{1}}}={\frac {V_{2}}{n_{2}}}}

The equation shows that, as the number of moles of gas increases, the volume of the gas also increases in proportion. Similarly, if the number of moles of gas is decreased, then the volume also decreases. Thus, the number of molecules or atoms in a specific volume of ideal gas is independent of their size or the molar mass of the gas.


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